HEATS 发表于 2010-9-12 19:11:09

常用蠕化元素的作用及吸收率

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<P><STRONG>元素</STRONG></P></TD>
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<P><STRONG>作用及吸收率</STRONG></P></TD></TR>
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<P>镁</P></TD>
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<LI>镁的作用是脱硫、脱氧、蠕化等。加入量如下: </LI></UL>
<P><SPAN lang=EN-US>Mg</SPAN><SUB><SPAN style="FONT-FAMILY: 宋体; mso-bidi-font-size: 10.5pt; mso-ascii-font-family: 'Times New Roman'; mso-hansi-font-family: 'Times New Roman'">总</SPAN></SUB><SPAN lang=EN-US>=Mg</SPAN><SUB><SPAN style="FONT-FAMILY: 宋体; mso-bidi-font-size: 10.5pt; mso-ascii-font-family: 'Times New Roman'; mso-hansi-font-family: 'Times New Roman'">损</SPAN></SUB><SPAN lang=EN-US>+Mg</SPAN><SUB><SPAN style="FONT-FAMILY: 宋体; mso-bidi-font-size: 10.5pt; mso-ascii-font-family: 'Times New Roman'; mso-hansi-font-family: 'Times New Roman'">残</SPAN></SUB></P>
<P>其中:Mg<SUB><SPAN style="FONT-SIZE: 10.5pt; FONT-FAMILY: 宋体; mso-ascii-font-family: 'Times New Roman'; mso-hansi-font-family: 'Times New Roman'; mso-font-kerning: 1.0pt; mso-bidi-font-family: 'Times New Roman'; mso-ansi-language: EN-US; mso-fareast-language: ZH-CN; mso-bidi-language: AR-SA">硫</SPAN></SUB>=0.76(S<SUB><SPAN style="FONT-SIZE: 10.5pt; FONT-FAMILY: 宋体; mso-ascii-font-family: 'Times New Roman'; mso-hansi-font-family: 'Times New Roman'; mso-font-kerning: 1.0pt; mso-bidi-font-family: 'Times New Roman'; mso-ansi-language: EN-US; mso-fareast-language: ZH-CN; mso-bidi-language: AR-SA">原</SPAN></SUB>- S<SUB><SPAN style="FONT-SIZE: 10.5pt; FONT-FAMILY: 宋体; mso-ascii-font-family: 'Times New Roman'; mso-hansi-font-family: 'Times New Roman'; mso-font-kerning: 1.0pt; mso-bidi-font-family: 'Times New Roman'; mso-ansi-language: EN-US; mso-fareast-language: ZH-CN; mso-bidi-language: AR-SA">残</SPAN></SUB>)</P>
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<LI>镁的吸收率(Mg<SUB><SPAN style="FONT-SIZE: 10.5pt; FONT-FAMILY: 宋体; mso-ascii-font-family: 'Times New Roman'; mso-hansi-font-family: 'Times New Roman'; mso-font-kerning: 1.0pt; mso-bidi-font-family: 'Times New Roman'; mso-ansi-language: EN-US; mso-fareast-language: ZH-CN; mso-bidi-language: AR-SA">硫</SPAN></SUB>和Mg<SUB><SPAN style="FONT-SIZE: 10.5pt; FONT-FAMILY: 宋体; mso-ascii-font-family: 'Times New Roman'; mso-hansi-font-family: 'Times New Roman'; mso-font-kerning: 1.0pt; mso-bidi-font-family: 'Times New Roman'; mso-ansi-language: EN-US; mso-fareast-language: ZH-CN; mso-bidi-language: AR-SA">残</SPAN></SUB>所占的比例)如下:一般30%左右; 铁液含S很低时,可达50%左右;冲入法,约30%~50%
<LI>单独用镁蠕化,Mg残0.0150%~0.020%,控制十分困难。生产中镁与钛或稀土合用,扩大镁蠕化含量范围 </LI></UL></TD></TR>
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<P>稀土</P></TD>
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<LI>蠕化含量范围大小依次如下: </LI></UL>
<P>La(镧)>Pr(镨)>Nd(钕)>Ce(铈)</P>
<UL>
<LI>稀土的作用是脱硫(到0.02%以下),去气(氧、氢、氮)蠕化。其中脱硫耗量如下: </LI></UL>
<P>轻稀土(平均原子量按142计)轻RE<SUB><SPAN style="FONT-SIZE: 10.5pt; FONT-FAMILY: 宋体; mso-ascii-font-family: 'Times New Roman'; mso-hansi-font-family: 'Times New Roman'; mso-font-kerning: 1.0pt; mso-bidi-font-family: 'Times New Roman'; mso-ansi-language: EN-US; mso-fareast-language: ZH-CN; mso-bidi-language: AR-SA">硫</SPAN></SUB>=3(S<SUB><SPAN style="FONT-SIZE: 10.5pt; FONT-FAMILY: 宋体; mso-ascii-font-family: 'Times New Roman'; mso-hansi-font-family: 'Times New Roman'; mso-font-kerning: 1.0pt; mso-bidi-font-family: 'Times New Roman'; mso-ansi-language: EN-US; mso-fareast-language: ZH-CN; mso-bidi-language: AR-SA">原</SPAN></SUB>- S<SUB><SPAN style="FONT-SIZE: 10.5pt; FONT-FAMILY: 宋体; mso-ascii-font-family: 'Times New Roman'; mso-hansi-font-family: 'Times New Roman'; mso-font-kerning: 1.0pt; mso-bidi-font-family: 'Times New Roman'; mso-ansi-language: EN-US; mso-fareast-language: ZH-CN; mso-bidi-language: AR-SA">残</SPAN></SUB>)</P>
<P>重稀土(平均原子量按108计)重RE<SUB><SPAN style="FONT-SIZE: 10.5pt; FONT-FAMILY: 宋体; mso-ascii-font-family: 'Times New Roman'; mso-hansi-font-family: 'Times New Roman'; mso-font-kerning: 1.0pt; mso-bidi-font-family: 'Times New Roman'; mso-ansi-language: EN-US; mso-fareast-language: ZH-CN; mso-bidi-language: AR-SA">硫</SPAN></SUB>=2.2(S<SUB><SPAN style="FONT-SIZE: 10.5pt; FONT-FAMILY: 宋体; mso-ascii-font-family: 'Times New Roman'; mso-hansi-font-family: 'Times New Roman'; mso-font-kerning: 1.0pt; mso-bidi-font-family: 'Times New Roman'; mso-ansi-language: EN-US; mso-fareast-language: ZH-CN; mso-bidi-language: AR-SA">原</SPAN></SUB>- S<SUB><SPAN style="FONT-SIZE: 10.5pt; FONT-FAMILY: 宋体; mso-ascii-font-family: 'Times New Roman'; mso-hansi-font-family: 'Times New Roman'; mso-font-kerning: 1.0pt; mso-bidi-font-family: 'Times New Roman'; mso-ansi-language: EN-US; mso-fareast-language: ZH-CN; mso-bidi-language: AR-SA">残</SPAN></SUB>)</P>
<P>钇(原子量88.9) Y<SUB><SPAN style="FONT-SIZE: 10.5pt; FONT-FAMILY: 宋体; mso-ascii-font-family: 'Times New Roman'; mso-hansi-font-family: 'Times New Roman'; mso-font-kerning: 1.0pt; mso-bidi-font-family: 'Times New Roman'; mso-ansi-language: EN-US; mso-fareast-language: ZH-CN; mso-bidi-language: AR-SA">硫</SPAN></SUB>=1.8(S<SUB><SPAN style="FONT-SIZE: 10.5pt; FONT-FAMILY: 宋体; mso-ascii-font-family: 'Times New Roman'; mso-hansi-font-family: 'Times New Roman'; mso-font-kerning: 1.0pt; mso-bidi-font-family: 'Times New Roman'; mso-ansi-language: EN-US; mso-fareast-language: ZH-CN; mso-bidi-language: AR-SA">原</SPAN></SUB>- S<SUB><SPAN style="FONT-SIZE: 10.5pt; FONT-FAMILY: 宋体; mso-ascii-font-family: 'Times New Roman'; mso-hansi-font-family: 'Times New Roman'; mso-font-kerning: 1.0pt; mso-bidi-font-family: 'Times New Roman'; mso-ansi-language: EN-US; mso-fareast-language: ZH-CN; mso-bidi-language: AR-SA">残</SPAN></SUB>)</P>
<P>稀土还细化共晶团,中和干扰元素,增大过冷却度,稳定碳化物。但镧减少碳化物,减少白口倾向</P>
<P>3.稀土在铁液重的吸收率约60%</P></TD></TR>
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<P>钙</P></TD>
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<P>1.钙的脱硫能力小于铈大于镁、脱氧能力大于铈更大于镁</P>
<P>2.对于低硫(S<0.008%),钙可使石墨蠕化量的范围最宽(VG50%~100%)</P>
<P>3.钙在铁液中的吸收率仅3%左右,获得同样蠕虫状石墨,钙的加入量几乎比稀土加入量多7倍。蠕化能力差</P></TD></TR></TBODY></TABLE>
               
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